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C9 Atm ChemistryAQA GCSE Chemistry · 8462 (Triple)

Earth's Atmosphere

History and composition of the atmosphere, evolution over time, evidence for changes.

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CognitoEarth's atmosphere — evolution and composition
Key facts & methods

Current composition of the atmosphere

  • Nitrogen (N2): approximately 78%.
  • Oxygen (O2): approximately 21%.
  • Argon (Ar): approximately 1%.
  • Carbon dioxide (CO2): approximately 0.04% (but increasing).
  • Water vapour: variable (up to ~2%).
  • Noble gases (He, Ne, Kr, Xe): trace amounts.

Evolution of the atmosphere

  • 4.6 billion years ago: Earth formed. Early atmosphere mainly CO2, water vapour and ammonia (from volcanic activity). Very little or no oxygen.
  • Volcanic activity: released CO2, H2O vapour, N2, SO2 into atmosphere.
  • Water vapour condensed: formed oceans. CO2 dissolved into oceans and precipitated as calcium carbonate.
  • Photosynthesis: algae and early plants produced O2 by photosynthesis — O2 levels rose over 2.7 billion years.
  • Nitrogen: increased as ammonia was converted by bacteria and by lightning.

Evidence for atmosphere changes

  • Rocks: carbonate rocks (limestone) = evidence that CO2 was removed from atmosphere.
  • Iron-banded formations: formed before O2 rose (iron oxidised as O2 appeared).
  • Fossils of early photosynthetic organisms (stromatolites, cyanobacteria).
  • Gas bubbles in ancient ice cores show past atmospheric composition.
  • Mathematical models based on volcanic activity, weathering and biological processes.

Role of key processes

  • Photosynthesis: removes CO2, produces O2. Vital for rising oxygen levels.
  • Respiration and combustion: consume O2, release CO2.
  • Dissolution in oceans: CO2 dissolves — critical for reducing early CO2 levels.
  • Formation of fossil fuels: ancient organisms absorbed CO2 — now released by combustion.
  • Maintaining current balance: photosynthesis and respiration broadly in balance (before human activity).
Exam questions — 4 questions · 10 marks · AQA 8462 style
Show all working — the AI marks against the AQA mark scheme. Method marks awarded for correct working even if the final answer is wrong.
1 markAtmosphere compositionAQA 8462 style

Approximately what percentage of the current atmosphere is nitrogen?

A 21%
B 50%
C 78%
D 100%
3 marksEvolution of atmosphereAQA 8462 P1 style

Explain how the level of oxygen in the atmosphere increased over billions of years. (3 marks)

Hint: Start with: early atmosphere had no O2. Explain: photosynthesis by early organisms produced O2. Over billions of years O2 accumulated.
+30 XP
1 markCO2 decreaseAQA 8462 style

Which of the following is NOT a reason why CO2 levels decreased in the early atmosphere?

A CO2 dissolved in oceans
B Photosynthesis removed CO2
C CO2 was converted to oxygen by volcanic activity
D Formation of carbonate rocks (limestone) locked up carbon
3 marksRole of oceansAQA 8462 style

Explain how the formation of oceans helped reduce the level of CO2 in the early atmosphere. (3 marks)

Hint: Chain: water vapour condenses → oceans form → CO2 dissolves in ocean water → carbonate rocks form → CO2 removed from atmosphere.
+30 XP

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